Going back in time with a material

Carbon 14 is a radioactive isotope present in every living organism. When the organism dies, it decays at a known rate: measuring what remains makes it possible to estimate the age of the material, up to about 50,000 years.
Applied to a work, carbon 14 dating tells us the age of the support (wood, canvas, paper, parchment), of an element in ivory or bone, of a textile. It does not date the paint itself, except in rare cases of isolable organic binders.
It costs from €600 to €1,100 excl. VAT and takes three to five weeks, with a sample of a few milligrams.
Dating in figures
Datable materials
| Material | Datable? | Remark |
|---|---|---|
| Wood (support, sculpture) | Yes | Date of felling of the tree, not of the sculpture |
| Linen or cotton canvas | Yes | Date of harvest of the fibre |
| Paper, parchment | Yes | Date of manufacture of the material |
| Ivory, bone, horn | Yes | Date of the animal's death |
| Metals, stone, ceramics | No | No organic carbon |
Course of a dating
- Choice of sample
Discreet area, minimal quantity, in the presence of the expert.
- Pre-treatment
Removal of contaminations (glues, restorations).
- Measurement
Accelerator mass spectrometry (AMS).
- Calibration
Conversion of radiocarbon age into calendar age.
- Interpretation
The expert compares the interval with the expected dating.



Date of the material, not of the work
The problem of calibration plateaus
The calibration curve has “plateaus”: between about 1650 and 1950, several calendar ages give the same radiocarbon age. Dating materials from this period is therefore not very discriminating.
On the other hand, for materials after 1955, the “nuclear bomb” left a signature in the atmosphere that carbon 14 detects precisely: a work supposedly earlier but whose support contains this signal is necessarily recent.
Useful or not very useful dating

Useful
Antiquity, Middle Ages, old tribal arts- Narrow interval possible
- Strong exclusion value
- Little calibration plateau
For works more than 400 years old.

Not very useful
1650 – 1950- Calibration plateaus
- Interval too wide
- Other methods preferable
To be avoided, unless a post-1955 signal.
Case study: a statue said to be ancient
A wood younger than expected
A wooden statue attributed to West Africa and dated to the 18th century is analysed.
- A sample of three milligrams is taken under the base.
- The dating gives an interval between 1955 and 1980.
- The expert concludes it is a work of the second half of the 20th century.
The certificate of authenticity of the stated period is refused.
From request to result
- Agreement
Analysis validated by the applicant.
- Sampling
In the presence of the expert.
- Laboratory
Pre-treatment and measurement.
- Result
Report and interpretation.



A methodological precaution

« Carbon 14 says when the tree died. It is for the expert to say when the statue was carved. »
Vocabulary of dating
- AMS
- Accelerator mass spectrometry, precise measurement of carbon 14.
- Calibration
- Conversion of a radiocarbon age into a calendar age.
- Plateau
- Zone of the curve where several ages give the same result.
- Bomb peak
- Atmospheric signal after 1955.
Frequently asked questions
Does dating damage the work?
It requires a sample of a few milligrams, in a discreet and documented area.
Can the paint be dated?
Rarely: it is rather the support that is dated.
Is it mandatory?
No, it is proposed by the expert when it is useful.
Can dating prove authenticity?
No, it can only exclude it or make it plausible.
Useful documents
Contacts

See scientific imaging
Image credits (16)
- Taj Mahal, Back View of the Rest-House, with Figure, Dr. John Murray (c. 1858–1862) — Cleveland Museum of Art, CC0 1.0
- The Shepherd, Paulus Potter (1644) — Cleveland Museum of Art, CC0 1.0
- The Judgment of Midas, Nicolaes Clock (1589) — Cleveland Museum of Art, CC0 1.0
- Portrait Bust of a Man (27 BCE–14 CE) — Cleveland Museum of Art, CC0 1.0
- Telescoping basket (1800's) — Cleveland Museum of Art, CC0 1.0
- Carpenter's Plane (1400s) — Cleveland Museum of Art, CC0 1.0
- Medal: In Commemoration of the Fiftieth Anniversary - The Warner and Swasey Company, Victor D. Brenner (1930) — Cleveland Museum of Art, CC0 1.0
- Self-Portrait, John I Smart (1802) — Cleveland Museum of Art, CC0 1.0
- Flowers and Trees of the Four Seasons, Watanabe Shikō (early-mid 1700s) — Cleveland Museum of Art, CC0 1.0
- Study for "Bathers at Asnières", Georges Seurat (c. 1883–84) — Cleveland Museum of Art, CC0 1.0
- Leaf from a Psalter and Prayerbook: Ornamental Border with Carnations, a Thistle, and a Cook Ladling Soup (verso) (c. 1524) — Cleveland Museum of Art, CC0 1.0
- Small Mosque in the Kaiserbagh, Felice A. Beato (1858) — Cleveland Museum of Art, CC0 1.0
- Jar with Stamped Decoration (1400s) — Cleveland Museum of Art, CC0 1.0
- Fish or Seal Club (X’ús’) (late 1800s–early 1900s) — Cleveland Museum of Art, CC0 1.0
- Annunciation to the Shepherds: Leaf from a Book of Hours (1 of 6 Excised Leaves), Henri d'Orquevaulx (c. 1420–30) — Cleveland Museum of Art, CC0 1.0
- Portrait of a Man, Italian Painter — The Metropolitan Museum of Art, CC0 1.0
Cleveland Museum of Art · CC0 1.0
Spectroscopic analysesX-ray fluorescence, Raman and infrared: identify pigments, metals and binders to confirm or contradict the dating of a work.›
Certificates of authenticityThe OIMAP certificate of authenticity establishes, through independent expertise and scientific analysis, that the work is indeed the one claimed.›
Partner laboratoriesThe network of 24 laboratories that carry out the scientific analyses of cases: spectroscopy, dating and imaging.›